Journal of the Less-Common Metals p. 75 - 83 (1988)
Update date:2022-08-06
Topics:
Guelin
Ravez
Hagenmuller
Six new non-stoichiometric oxyfluoride phases, the compositions of which are related to LiMo//3 (M EQUVLNT Nb, Ta), have been prepared. They belong either to the LiNbO//3-LiF-NbO//2F or the LiTaO//3-LiF-TaO//2F system. Thermal and dielectric measurements have shown each composition to present a ferroelectric-paraelectric transition. The Curie temperature T//C increases with cationic excess and decreases with cationic deficit. The F-O substitution has only a small influence on T//C.
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