ALKYLIDENE LACTONE SYNTHESIS

DOI: 10.1016/S0040-4020(01)87132-5

Source and publish data:

Tetrahedron p. 5203 - 5214 (1991)

Update date:2022-07-30

Topics:

Authors:

Haaima, Gerald

Lynch, Mary-Jeanne

Routledge, Anne

Weavers, Rex T.

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Article abstract of DOI:10.1016/S0040-4020(01)87132-5

The iodoalkylidene lactones formed by reaction of alkenes with acetylenic acids in the presence of N-iodosuccinimide and subsequent free radical cyclisation, can be de-iodinated photochemically or alkylated with lithium diorganocuprate reagents to yield a variety of α-alkylidene lactones.

Full text of DOI:10.1016/S0040-4020(01)87132-5

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