Diene-dienophile hydrogen-bonding control of diels-alder reactions with dienes bearing a remote stereogenic center. Amplification of the receptor nature of dienes by conformational tuning leading to high diastereofacial discrimination

DOI: 10.1021/ja00020a026

Source and publish data:

Journal of the American Chemical Society p. 7630 - 7640 (1991)

Update date:2022-08-05

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Authors:

Tripathy, Rabindranath

Carroll, Patrick J.

Thornton, Edward R.

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Article abstract of DOI:10.1021/ja00020a026

The Diels-Alder reactions of 1-(O-methylmandeloxy)butadiene and its analogues, bearing a remote stereogenic center, have been studied to elucidate the stereoselective control elements. Several model dienes (5a-5f) have been designed to enhance the facial

Full text of DOI:10.1021/ja00020a026

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