Practical synthesis of optically pure 3,4-epoxy-5-methyldihydro-2(3H)-furanones from D-xylose by regio- and stereo-selective functionalization

DOI: 10.1016/S0008-6215(00)90532-9

Source and publish data:

Carbohydrate Research p. 87 - 93 (1991)

Update date:2022-08-04

Topics:

Authors:

Hildebrandt, Bernhard

Nakamura, Yoshikazu

Ogawa, Seiichiro

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Article abstract of DOI:10.1016/S0008-6215(00)90532-9

The known 1,2-O-isopropylidene-5-O-p-tolylsulfonyl-α-D-xylofuranose was converted into its 3-p-nitrobenzoate (13a) and 3-methanesulfonate (13b). (-)-(3S,4S,5R)-3,4-Epoxy-5-methyldihydro-2(3H)-furanone <(-)-8> was synthesized from 13a in 5 steps by convers

Full text of DOI:10.1016/S0008-6215(00)90532-9

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