C-C Bond Formation via Carbon-Centered Radicals Generated from Dicarbonyl(η5-cyclopentadienyl)organoiron Complexes

DOI: 10.1002/hlca.19910740524

Source and publish data:

Helvetica Chimica Acta p. 1143 - 1155 (1991)

Update date:2022-08-05

Topics: applications C-C Bond Formation Radical Generation

Authors:

Giese, Bernd

Gebhard, Thoma

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Article abstract of DOI:10.1002/hlca.19910740524

Irradiation of benzyldicarbonyl(η⁵-cyclopentadienyl)iron complex (2) leads to homolytic cleavage of the Fe-C bond.In the presence of activated alkenes, radical addition occurs, and both saturated and unsaturated addition products 7-9 are formed.Photolysis of alkyliron complexes 2, 3, and 20 in the presence of acrylonitrile leads to the same products as the irradiation of the respective acyliron complexes 28-30.This indicates that, under photolytical conditions, alkyl and acyl complexes are in equilibrium with each other.

Full text of DOI:10.1002/hlca.19910740524

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