Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1229 - 1234 (1991)
Update date:2022-08-03
Topics:
Dzhemilev, U. M.
Sultanov, R. M.
Gaimaldinov, R. G.
Tolstikov, G. A.
The reactions of magnesium-cyclopentane with styrene and of 2,4-diphenylmagnesium-cyclopentane with ethylene in the presence of catalytic amounts of Cp2ZrCl2 leading to the formation of 2-phenylmagnesium-cyclopentane and 2,4-diphenylmagnesium-cyclopentane, were studied for the first time.It was found that zirconocylopentanes, are intermediates in this reaction, which are formed both from magnesium-cycloalkanes and from α-olefins and Cp2ZrCl2.A possible mechanism of the reactions studied has been proposed.
View MoreCHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD
website:http://www.czyys.com
Contact:0086-519-88802789
Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD
Contact:29-63685658 63685359
Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
Landz International Company Ltd.
Contact:0086-21-58891610
Address:985 Dongfang Road, Pudong, Shanghai 200122 China
Contact:+86-633-8332928
Address:No.1,Huanghai Yilu.Rizhao,Shandong
Contact:86-513-84128750/13773795976
Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Doi:10.1021/jacs.6b11626
(2017)Doi:10.1016/0008-6215(88)84118-1
(1988)Doi:10.1016/S0040-4039(00)90541-0
(1967)Doi:10.1039/P19960002827
(1996)Doi:10.1021/acs.orglett.6b02021
(2016)Doi:10.1002/hlca.19910740505
(1991)
