Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1229 - 1234 (1991)
Update date:2022-08-03
Topics:
Dzhemilev, U. M.
Sultanov, R. M.
Gaimaldinov, R. G.
Tolstikov, G. A.
The reactions of magnesium-cyclopentane with styrene and of 2,4-diphenylmagnesium-cyclopentane with ethylene in the presence of catalytic amounts of Cp2ZrCl2 leading to the formation of 2-phenylmagnesium-cyclopentane and 2,4-diphenylmagnesium-cyclopentane, were studied for the first time.It was found that zirconocylopentanes, are intermediates in this reaction, which are formed both from magnesium-cycloalkanes and from α-olefins and Cp2ZrCl2.A possible mechanism of the reactions studied has been proposed.
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Doi:10.1021/jacs.6b11626
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(1991)
