Correction to: Nickel-catalyzed enantioselective reductive cross-coupling of styrenyl aziridines (Journal of the American Chemical Society (2017) 139 (5688-5691) DOI: 10.1021/jacs.7b03448)

Article abstract of DOI:10.1021/jacs.8b05650

Table of Contents. The enantiomer of the BiOx ligand that delivers the indicated absolute configuration of product is (R,R)-(4-heptyl)BiOx. The corrected graphic is shown below: Page 5690. The absolute configuration of ligand L7 (4-heptyl- BiOx) was misas

Full text of DOI:10.1021/jacs.8b05650

Addition/Correction
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Cite This: J. Am. Chem. Soc. XXXX, XXX, XXX−XXX
Correction to “Nickel-Catalyzed Enantioselective Reductive
Cross-Coupling of Styrenyl Aziridines”
Brian P. Woods, Manuel Orlandi, Chung-Yang Dennis Huang, Matthew S. Sigman,*
and Abigail G. Doyle*
J. Am. Chem. Soc. 2017, 139, 5688−5691. DOI: 10.1021/jacs.7b03448
S
* Supporting Information
Table 3. Scope of Stereoconvergent Reaction
Table of Contents. The enantiomer of the BiOx ligand
that delivers the indicated absolute configuration of prod-
uct is (R,R)-(4-heptyl)BiOx. The corrected graphic is shown
below:
Page 5690. The absolute configuration of ligand L7 (4-heptyl-
BiOx) was misassigned. The updated assignment requires cor-
rections to Figure 2 and Table 3.
The (S)-enantiomer of cross-coupled product 7 is obtained
using the (S,S)-series of BiOx ligands. The corrected Figure 2 is
given here.
a
b
Yield of isolated product (3 equiv of iodide). Determined by chiral
c
d
HPLC. 10 mol % Ni, 12 mol % L7. No TMSCl added.
Supporting Information. Page S2. The (R,R)- not the (S,S)-
BiOx ligands L7-L9 were used for the studies in Figure S1.
Pages S4 and S5. (R,R)-L7, not (S,S)-L7, was used for the scope
studies in Tables S1, S2, and S4. Page S8. The (S)-enantiomer of
cross-coupled product 7 is obtained using the (S,S)-L7 ligand in
Scheme S5. Pages S12 and S13. The absolute configurations of
structures S2-S5 have been corrected.
Figure 2. Impact of BiOx ligand substituent on asymmetric cross-
coupling.
Page 5690. (R,R)-L7, not (S,S)-L7, was used for the scope
studies in Table 3. The corrected Table 3 is shown here. We
thank the Reisman laboratory for sharing information leading
to this reassignment.
© XXXX American Chemical Society
A
DOI: 10.1021/jacs.8b05650
J. Am. Chem. Soc. XXXX, XXX, XXX−XXX

Journal of the American Chemical Society
Addition/Correction
ASSOCIATED CONTENT
* Supporting Information
The Supporting Information is available free of charge on the
ACS Publications website at DOI: 10.1021/jacs.8b05650.
■
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Experimental procedures, additional reaction optimiza-
tion, and spectroscopic data for all new compounds
(corrected) (PDF)
B
DOI: 10.1021/jacs.8b05650
J. Am. Chem. Soc. XXXX, XXX, XXX−XXX