Synlett p. 367 - 370 (2012)
Update date:2022-08-04
Topics:
Zhang, Youlai
Tanimoto, Hiroki
Nishiyama, Yasuhiro
Morimoto, Tsumoru
Kakiuchi, Kiyomi
A novel photolabile protecting group, thiochromone S,S-dioxide, containing the diazomethyl group for protection of phosphate derivatives is described. Deprotection of the successfully protected phosphate derivatives proceeded smoothly under photoirradiation using an ultrahigh-pressure mercury lamp to recover the corresponding phosphates quantitatively, and the photoproduct derived from the thiochromone derivative showed high fluorescence intensity. Georg Thieme Verlag Stuttgart · New York.
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(2012)