Tetrahedron Letters p. 4243 - 4246 (1991)
Update date:2022-07-31
Topics:
Farina, Vittorio
Roth, Gregory P.
Vinyl triflates couple smoothly with a variety of arylstannanes provided a polar, aprotic solvent is used in conjunction with a "ligandless" palladium catalyst, or catalytic system involving weak ligands such as triphenylarsine. Commonly employed ligands, for example, triphenylphosphine, were found to strongly inhibit the coupling.
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