Journal of the Chemical Society, Dalton Transactions p. 2703 - 2706 (1991)
Update date:2022-08-03
Topics:
Kawamura, Takashi
Ebihara, Masahiro
Katayama, Hiroaki
Nishikawa, Hiroyuki
Yamabe, Tokio
(Dithiobenzoato)(trithioperoxybenzoato)platinum(II) was obtained through reactions of a = 16.629(2), b = 6.296(1), c = 29.182(2) Angstroem, β = 91.85(1) deg, and Z = 8.The complex has four- and five-membered chelate rings with a normal square-planar PtS4 arrangement.The stucture consists of dimers with a configuration in which the five-membered chelate ring of one molecule lies over the four-membered ring of the other.An extended-Hueckel molecular orbital calculation suggests intradimer charge-transfer interaction as the driving force for the formnation of the dimer.The diffuse reflectance spectrum of a powder sample of the complex gives new bands which are absent from the solution spectra.
Shanghai Yudiao Chemistry Technology Co.,Ltd
Contact:0086-18964703211
Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
Hangzhou Showland Technology Co., Ltd.
Contact:86-571-88920516
Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Shanghai shibo Chemical Co., Ltd
Contact:+86-021-60753516
Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Huaihua Baohua Biotechnology Co.,Ltd
website:http://www.baochengchem.com
Contact:86-519-82698291
Address:HouYang chemical development zone,Jintan,Jiangsu,China (213200)
Contact:+86 755 26588093
Address:No.9 Linkong West Street, Hengdian Street, Huangpi District, Wuhan City, China.
Doi:10.1002/ardp.201100138
(2012)Doi:10.1021/ma300640n
(2012)Doi:10.1007/BF00957859
(1990)Doi:10.1007/BF01172291
(1991)Doi:10.1246/cl.130575
(2013)Doi:10.1016/S0040-4039(00)60524-5
(1993)
