Enantioselective Vinylation of Aldehydes with Chiral β-Silylphosphorus Ylides

DOI: 10.1039/c39910001390

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1390 - 1392 (1991)

Update date:2022-07-29

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Authors:

Iio, Hideo

Fujii, Akio

Ishii, Masahiro

Tokoroyama, Takashi

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Article abstract of DOI:10.1039/c39910001390

Both enantiomers of diastereoisomeric <1-(N,N-dimethylaminoethyl)ferrocenyl>diphenyl(2-diphenylmethylsilylethylidene)phosphorane 3 and 4 are prepared; their reaction with benzaldehyde and aliphatic aldehydes is found to give vinylation products with varia

Full text of DOI:10.1039/c39910001390

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