Sequential Vinylcyclopropylcarbene and Anionic Oxy-cope Rearrangements: An Expedient Synthesis of Nine-Membered Rings

DOI: 10.1016/S0040-4039(00)97672-X

Source and publish data:

Tetrahedron Letters p. 4547 - 4550 (1990)

Update date:2022-07-30

Topics:

Authors:

Herndon, James W.

McMullen, Leonard A.

Daitch, Charles E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97672-X

5-Alkenyl-2-methoxy-2-cyclopentenones, readily available from thermolysis of 2-alkenylcyclopropylcarbene-chromium complexes, can be converted to nine-membered rings by treatment with vinylcerium reagents and subsequent anionic oxy-Cope rearrangement.

Full text of DOI:10.1016/S0040-4039(00)97672-X

Products guided by the article

Product name:2-Methoxy-5-methyl-1-((E)-styryl)-5-vinyl-cyclopent-2-enol

Cas No:137675-60-6

R&D Labs maybe for 137675-60-6

Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin
Lonwin Chemical Group Limited

website:http://www.lonwinchem.com

Contact:Tel: 86-21-59858395

Address:No#966,Huaxu Road,Shanghai 201702,P.R.China
Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Chongqing Shuangfeng Chemical Co.,Ltd

Contact:+86-23-49850156

Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Hangzhou Share Chemical Co., Ltd(expird)

Contact:+86-57187093700

Address:Hang Xing Road

Relevant to this article

Diastereospecific synthesis of D-and L-allo-threonines and trichlorinated derivatives suitable for the preparation of tritium labelled material

Doi:10.1016/S0040-4039(00)74479-0
(1991)
Total Synthesis of Cervinomycin A1-trimethyl Ether and Cervinomycin A2-methyl Ether

Doi:10.1016/S0040-4039(00)93465-8
(1991)
Synthesis and biological evaluation of benzocyclooctene-based and indene-based anticancer agents that function as inhibitors of tubulin polymerization

Doi:10.1039/c6md00459h
(2016)
Doi:10.1021/jo01288a003
(1967)
REACTION OF 4,5-DIHALOPYRIMIDINES WITH 2-TOSYLMETHYLAZAHETARENES - ONE-STEP METHOD FOR OBTAINING CONDENSED POLYNUCLEAR SYSTEMS

Doi:10.1007/BF00472529
(1991)
Syntheses, structures, and fluorescent and magnetic properties of four metal–organic coordination polymers constructed from dicarboxylate ligands

Doi:10.1080/24701556.2020.1862213
(2021)

Article Doi