Tetrahedron Letters p. 4547 - 4550 (1990)
Update date:2022-07-30
Topics:
Herndon, James W.
McMullen, Leonard A.
Daitch, Charles E.
5-Alkenyl-2-methoxy-2-cyclopentenones, readily available from thermolysis of 2-alkenylcyclopropylcarbene-chromium complexes, can be converted to nine-membered rings by treatment with vinylcerium reagents and subsequent anionic oxy-Cope rearrangement.
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