Kinetics of alkylhalocarbene rearrangements: Modulation by fluorine substituents

DOI: 10.1021/ja00029a025

Source and publish data:

Journal of the American Chemical Society p. 959 - 963 (1992)

Update date:2022-09-26

Topics:

Authors:

Moss, Robert A.

Ho, Guo-Jie

Liu, Weiguo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00029a025

Rate constants were measured by laser flash photolytic methods for hydrogen and carbon 1,2-migrations in four different alkylchlorocarbenes and in the analogous alkylfluorocarbenes. The carbenes, products, and rate constants (^-1 were as follows

Full text of DOI:10.1021/ja00029a025

Products guided by the article

Product name:Benzene, [(2-fluoroethenyl)oxy]-, (Z)-

Cas No:137720-26-4

R&D Labs maybe for 137720-26-4

Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
ABA Chemicals (Shanghai) Limited

Contact:021- 5115 9199-232

Address:Suite 18D, #201 Ningxia Road,
Changzhou Litong Chemical Co., Ltd.

website:http://www.litonchem.com/

Contact:+86-519-86301238

Address:Laoba Rd, Hutang town Changzhou Jiangsu
Shanghai Dynamic Industrial Co.,Ltd.

website:http://www.shdynamic.com

Contact:86-021 3392 6680

Address:Room 805 Information Tower, No.1403 Minsheng Road, Pudong New Area, Shanghai 200135, P. R. China
CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County

Relevant to this article

Group 13 β-ketoiminate compounds: Gallium hydride derivatives as molecular precursors to thin films of Ga₂O₃

Doi:10.1021/ic3006794
(2012)
Reversible 1,3-anti/syn-stereochemical courses in copper-catalyzed γ-selective allyl-alkyl coupling between chiral allylic phosphates and alkylboranes

Doi:10.1021/ja302520h
(2012)
Hydrogen-bonded helical self-assembly of sterically-hindered benzyl alcohols: Rare isostructurality and synthon equivalence between alcohols and acids

Doi:10.1021/cg3001619
(2012)
Copper-mediated oxidative cross-coupling reaction of terminal alkynes with α-silyldifluoromethylphosphonates: An efficient method for α,α-difluoropropargylphosphonates

Doi:10.1021/ol301113v
(2012)
Electronic Paramagnetic Resonance Studies of Radical Pairs ->2 (M = Cr, Mo, W) trapped in Single Crystals of PPh4⁺HM(CO)5^-

Doi:10.1039/ft9918703121
(1991)
Synthesis of Enantiomerically Pure, P-1-Tethered Inositol Tetrakis(phosphate) Affinity Labels via a Ferrier Rearrangement

Doi:10.1021/ja00026a043
(1991)

Article Doi