Kinetics of alkylhalocarbene rearrangements: Modulation by fluorine substituents

DOI: 10.1021/ja00029a025

Source and publish data:

Journal of the American Chemical Society p. 959 - 963 (1992)

Update date:2022-09-26

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Authors:

Moss, Robert A.

Ho, Guo-Jie

Liu, Weiguo

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Article abstract of DOI:10.1021/ja00029a025

Rate constants were measured by laser flash photolytic methods for hydrogen and carbon 1,2-migrations in four different alkylchlorocarbenes and in the analogous alkylfluorocarbenes. The carbenes, products, and rate constants (^-1 were as follows

Full text of DOI:10.1021/ja00029a025

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