New Reactivity of Phosphirenes (Phosphacyclopropenes). Synthesis of Allenylphosphines and of Functional Phosphirenes.

DOI: 10.1016/S0040-4020(01)82319-X

Source and publish data:

Tetrahedron p. 6673 - 6680 (1991)

Update date:2022-09-26

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Authors:

Nief, F.

Mathey, F.

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Article abstract of DOI:10.1016/S0040-4020(01)82319-X

1-Mesityl 2,3-dimethylphosphirene 1 and 1-mesityl 2-methylphosphirene 4 can be easily prepared from mesityldichlorophosphine (MesPCl2), AlCl3, 2-butyne or propyne and Bu3P.Because of the steric bulk of the mesityl substituent, n-butyllithium no longer rea

Full text of DOI:10.1016/S0040-4020(01)82319-X

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