Asymmetric Syntheses of (R)-(-)-Muscone based on Diastereoselective Conjugate Addition

DOI: 10.1039/c39910001438

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1438 - 1439 (1991)

Update date:2022-08-05

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Authors:

Ogawa, Tomoyuki

Fang, Cheng-Lin

Suemune, Hiroshi

Sakai, Kiyoshi

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Article abstract of DOI:10.1039/c39910001438

(R)-(-)-Muscone was synthesized in a stereocontrolled manner via the stereoselective conjugate addition to a cyclic α,β-unsatureted ester of (R,R)-cyclohexane-1,2-diol accompanied by spontaneous Dieckmann condensation.

Full text of DOI:10.1039/c39910001438

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Product name:(Triphenyl-λ⁵-phosphanylidene)-acetic acid (1R,2R)-2-hydroxy-cyclohexyl ester

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