Regiochemistry of Boron Trifluoride Mediated Hydrolysis of Glycidyl Benzoates

DOI: 10.1246/cl.1991.1865

Source and publish data:

Chemistry Letters p. 1865 - 1868 (1991)

Update date:2022-07-29

Topics:

Authors:

Yoshitake, Makoto

Kobayashi, Hiroyuki

Yamamoto, Makoto

Kohmoto, Shigeo

Yamada, Kazutoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1991.1865

Hydrolysis of glycidyl benzoates in the presence of BF3*OEt2 in CH2Cl2 affords regioisomeric triol monobenzoates, their ratios remarkably change depending on the temperature particularly in the reaction of 3,3-dimethylglycidyl benzoate.

Full text of DOI:10.1246/cl.1991.1865

Products guided by the article

Product name:1,2,3-Butanetriol, 3-methyl-, 3-benzoate

Cas No:138240-13-8

R&D Labs maybe for 138240-13-8

Suzhou Time-chem Technologies Co., Ltd.

Contact:0512-63983931/68086856

Address:No. 1326 of Binhe Road, New District, Suzhou, Jiangsu, P. R. China
Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang
Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
JIEJIE GROUP CO.,LTD.

Contact:+86 021-51698675

Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
Shanghai Synmedia Chemical Co., Ltd

Contact:+86-21-38681880

Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China

Relevant to this article

Synthesis of novel 2-alkyl-4-substituted-amino-pyrazolo[3,4-d]pyrimidines as new leads for anti-bacterial and anti-cancer activity

Doi:10.1007/s00044-012-0084-0
(2013)
Synthesis of 1′-aryl-2′-(2-oxoindolin-3-yl)spiro[indoline-3, 5′-pyrroline]-2,3′-dione via one-pot reaction of arylamines, acetone, and isatins

Doi:10.1016/j.tetlet.2012.05.023
(2012)
Indolocarbazole-based ligands for ladder-type four-coordinate boron complexes

Doi:10.1021/ol301339y
(2012)
Mild and efficient syntheses of 1-aryl-3,4-dihydroisoquinolines and 1-aryl-3,4-dihydro-β-carbolines via regiospecific β-eliminations of the corresponding N-tosyl-1,2,3,4-tetrahydroisoquinolines and N-tosyl-1,2,3,4-tetrahydro-β-carbolines

Doi:10.1080/00397911.2011.568659
(2012)
Fluorescent phosphatidylinositol 4,5-bisphosphate derivatives with modified 6-hydroxy group as novel substrates for phospholipase C

Doi:10.1021/bi300637h
(2012)
Synthesis and biological evaluation of new curcumin derivatives as antioxidant and antitumor agents

Doi:10.1007/s00044-012-0116-9
(2013)

Article Doi