Regiochemistry of Boron Trifluoride Mediated Hydrolysis of Glycidyl Benzoates

DOI: 10.1246/cl.1991.1865

Source and publish data:

Chemistry Letters p. 1865 - 1868 (1991)

Update date:2022-07-29

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Authors:

Yoshitake, Makoto

Kobayashi, Hiroyuki

Yamamoto, Makoto

Kohmoto, Shigeo

Yamada, Kazutoshi

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Article abstract of DOI:10.1246/cl.1991.1865

Hydrolysis of glycidyl benzoates in the presence of BF3*OEt2 in CH2Cl2 affords regioisomeric triol monobenzoates, their ratios remarkably change depending on the temperature particularly in the reaction of 3,3-dimethylglycidyl benzoate.

Full text of DOI:10.1246/cl.1991.1865

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