Enzymes in Organic Synthesis: Remarkable Influence of a ? System on the Enantioselectivity in PPL Catalysed Monohydrolysis of 2-Substituted 1,3-Diacetoxypropanes.

DOI: 10.1016/S0957-4166(00)82383-6

Source and publish data:

Tetrahedron Asymmetry p. 721 - 724 (1990)

Update date:2022-07-29

Topics:

Authors:

Guanti, Giuseppe

Banfi, Luca

Narisano, Enrica

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Article abstract of DOI:10.1016/S0957-4166(00)82383-6

The results of PPL catalysed monohydrolysis of a series of 2-substituted-1,3-diacetoxypropanes showed that alkinyl and (E) alkenyl substituents led to improvement of yield and enantioselectivity, compared to their saturated analogues.On the contrary, (Z) alkenyl substituents provoked a net reversal of asymmetric induction.

Full text of DOI:10.1016/S0957-4166(00)82383-6

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