Enzymes in Organic Synthesis: Remarkable Influence of a ? System on the Enantioselectivity in PPL Catalysed Monohydrolysis of 2-Substituted 1,3-Diacetoxypropanes.

DOI: 10.1016/S0957-4166(00)82383-6

Source and publish data:

Tetrahedron Asymmetry p. 721 - 724 (1990)

Update date:2022-07-29

Topics:

Authors:

Guanti, Giuseppe

Banfi, Luca

Narisano, Enrica

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(00)82383-6

The results of PPL catalysed monohydrolysis of a series of 2-substituted-1,3-diacetoxypropanes showed that alkinyl and (E) alkenyl substituents led to improvement of yield and enantioselectivity, compared to their saturated analogues.On the contrary, (Z) alkenyl substituents provoked a net reversal of asymmetric induction.

Full text of DOI:10.1016/S0957-4166(00)82383-6

Products guided by the article

Product name:(R)-2-Benzyloxymethoxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-propan-1-ol

Cas No:138436-33-6

R&D Labs maybe for 138436-33-6

Heliosense Biotechnologies, Inc.

website:https://www.heliosense.com/

Contact:+86-592-5667290

Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo
Allright GC (Jinan) Biotechnology Ltd.

website:https://www.argcbiotech.com/

Contact:86-18405413579-

Address: No.27566 of Jingshiroad, Huaiyin District, Jinan City(250011), Shandong Province, China.
Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone
ABA Chemicals (Shanghai) Limited

Contact:021- 5115 9199-232

Address:Suite 18D, #201 Ningxia Road,

Relevant to this article

Highly potent macrocyclic BACE-1 inhibitors incorporating a hydroxyethylamine core: Design, synthesis and X-ray crystal structures of enzyme inhibitor complexes

Doi:10.1016/j.bmc.2012.05.039
(2012)
Asymmetric synthesis of L-diphenylalanine and L-9-fluorenylglycine via room temperature alkylations of a sultam-derived glycine imine

Doi:10.1016/0040-4039(91)80217-T
(1991)
Correlation of the absolute conformation of sec alcohols derived from macrocyclic lactones of resorcylic acid and their stereoselective transacetylation in organic solvents by Pseudomonas fluorescens lipase

Doi:10.1016/S0040-4020(01)85687-8
(1994)
Nucleophilic Additions to and Reductions of 5-Formyl- and 5-Acyl-2-isoxazolines (4,5-Dihydroisoxazoles): A Stereoselective Route to β,γ-Dihydroxy Ketones

Doi:10.1039/P19910002613
(1991)
Dioxiranes. 20. Preparation and properties of some new dioxiranes

Doi:10.1021/ja00030a032
(1992)
On the mode of Baker's yeast reduction of enantiomeric 4-acyl butanolides

Doi:10.1016/S0040-4020(01)96212-X
(1991)

Article Doi