Diastereoface differentiation in addition of lithium enolates to chiral α, β-epoxyaldehydes

DOI: 10.1016/S0040-4020(01)82375-9

Source and publish data:

Tetrahedron p. 5253 - 5266 (1993)

Update date:2022-07-29

Topics:

Authors:

Escudier, Jean-Marc

Baltas, Michel

Gorrichon, Liliane

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)82375-9

The aldolisation reaction of lithium ester enolates with chiral α,β-epoxyaldehydes 2a-2f has been investigated. The reaction proceeds with diastereofacial preference in favour of the anti isomer (anti: syn ≈ 4:1) and can be greatly enhanced in the case of

Full text of DOI:10.1016/S0040-4020(01)82375-9

Products guided by the article

Product name:(3R,4S,5R)-tert-butyl <6-(benzyloxy)-4,5-epoxy-3-hydroxy>hexanoate

Cas No:138810-82-9

R&D Labs maybe for 138810-82-9

Xi'an Costrong Pharmaceutical Co., Ltd.

Contact:029- 68576496

Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China
NINGBO YINLIANG FOREIGN TRADE CO., LTD.

Contact:+86-574-87834016 / 87898057

Address:23F NO.666JINYU ROAD,YINGZHOU DISTRICT,NINGBO.CHINA
GM CHMICAL CO., LTD

Contact:0086-21-80264647

Address:RM 202, NO 1602 West Zhongshan Rd, Shanghai, China
Huaihua Baohua Biotechnology Co.,Ltd

website:http://www.baochengchem.com

Contact:86-519-82698291

Address:HouYang chemical development zone,Jintan,Jiangsu,China (213200)
GN chemicals co.,ltd

Contact:86 311 85902108 / 85902109

Address:room 1001-1005 ,huanghe Road ,shijiazhuang ,China

Relevant to this article

Replacing -CH₂CH₂- with -CONH- does not significantly change rates of charge transport through Ag^TS-SAM//Ga ₂O₃/EGaIn junctions

Doi:10.1021/ja301778s
(2012)
New Aryl-1,3-thiazole-4-carbohydrazides, Their 1,3,4-Oxadiazole-2-thione, 1,2,4-Triazole, Isatin-3-ylidene and Carboxamide Derivatives. Synthesis and Anti-HIV Activity

Doi:10.5560/ZNB.2012-0095
(2012)
Syntheses, structures, and electronic and optical properties of platinum(II) complexes of 1,3-bis(imino)benzene-derived pincer ligands

Doi:10.1021/om3003152
(2012)
Regioselective ring-opening of aziridines with diselenides and disulfides using the Zn/AlCl₃ system

Doi:10.1080/17415993.2011.551938
(2011)
Photoinduced vectorial electron transfer in multilayered Langmuir-Blodgett films of porphyrin and phtalocyanine derivatives

Doi:10.1134/S0036024410070253
(2010)
LC-MS based quantification of 2′-ribosylated nucleosides Ar(p) and Gr(p) in tRNA

Doi:10.1039/c1cc11011j
(2011)

Article Doi