Diastereoface differentiation in addition of lithium enolates to chiral α, β-epoxyaldehydes

DOI: 10.1016/S0040-4020(01)82375-9

Source and publish data:

Tetrahedron p. 5253 - 5266 (1993)

Update date:2022-07-29

Topics:

Authors:

Escudier, Jean-Marc

Baltas, Michel

Gorrichon, Liliane

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Article abstract of DOI:10.1016/S0040-4020(01)82375-9

The aldolisation reaction of lithium ester enolates with chiral α,β-epoxyaldehydes 2a-2f has been investigated. The reaction proceeds with diastereofacial preference in favour of the anti isomer (anti: syn ≈ 4:1) and can be greatly enhanced in the case of

Full text of DOI:10.1016/S0040-4020(01)82375-9

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Product name:(3R,4S,5R)-tert-butyl <6-(benzyloxy)-4,5-epoxy-3-hydroxy>hexanoate

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