A MECHANISTIC STUDY OF PYRROLE FORMATION IN THE HBF4-CATALYZED THERMOLYSIS OF CYCLOPROPYL KETIMINES.

DOI: 10.1016/0040-4039(91)85058-D

Source and publish data:

Tetrahedron Letters p. 7127 - 7130 (1991)

Update date:2022-08-04

Topics:

Authors:

Wasserman, Harry H.

Fukuyama, James M.

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Article abstract of DOI:10.1016/0040-4039(91)85058-D

A study of the HBF4-catalyzed rearrangement of 1-(1-piperidino)cyclopropyl ketimines to 2-substituted pyrroles has been conducted using carbon-13 labeled starting material.The results support the formation of a bicyclic aziridine-containing intermediate.

Full text of DOI:10.1016/0040-4039(91)85058-D

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