Platinum-Catalyzed Novel Reactions of Nitriles and an Azirine with o-Bis(dimethylsilyl)benzene

DOI: 10.1246/cl.1992.45

Source and publish data:

Chemistry Letters p. 45 - 48 (1992)

Update date:2022-07-29

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Authors:

Reddy, N. Prabhakar

Uchimaru, Yuko

Lautenschlager, Hans-Juergen

Tanaka, Masato

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Article abstract of DOI:10.1246/cl.1992.45

Nitriles and 2-phenylazirine underwent dehydrogenative double silylation with o-bis(dimethylsilyl)benzene in the presence of (ethylene)bis(triphenylphosphine)-platinum catalyst to give silyl enamines and imines in excellent yields.

Full text of DOI:10.1246/cl.1992.45

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