Studies on Aconitum species. XV. Deoxygenation reaction of aconitine type alkaloids

DOI: 10.1248/cpb.39.2803

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2803 - 2806 (1991)

Update date:2022-09-26

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Authors:

Mori Mori

Murayama

Bando Bando

Kawahara

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Article abstract of DOI:10.1248/cpb.39.2803

Mesaconitine (1) in tetrahydrofuran reacted with sodium hydride, a catalytic amount of imidazole, carbon disulfide and methyl iodide at room temperature to give the di-O-(S-methyl)thiocarbonate (5). The reductive cleavage of 5 with tri-n-butyltin hydride

Full text of DOI:10.1248/cpb.39.2803

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