Studies on Aconitum species. XV. Deoxygenation reaction of aconitine type alkaloids

DOI: 10.1248/cpb.39.2803

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2803 - 2806 (1991)

Update date:2022-09-26

Topics:

Authors:

Mori Mori

Murayama

Bando Bando

Kawahara

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.39.2803

Mesaconitine (1) in tetrahydrofuran reacted with sodium hydride, a catalytic amount of imidazole, carbon disulfide and methyl iodide at room temperature to give the di-O-(S-methyl)thiocarbonate (5). The reductive cleavage of 5 with tri-n-butyltin hydride

Full text of DOI:10.1248/cpb.39.2803

NII-Electronic Library Service

Products guided by the article

Product name:3-O-(S-methyl)thiocarbonyljesaconitine

Cas No:139617-12-2

R&D Labs maybe for 139617-12-2

Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Shanghai Gsyn Chemical Co.,Ltd.

Contact:86-021-67158290

Address:86-021-67158291
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China
Hangzhou Zhenghan Biological Technology Co., Ltd.

Contact:86-571-88781753

Address:liangzhu yuhang hangzhou city

Relevant to this article

Addition of 1,2-dihaloperfluoroalkanes to alkenes initiated by dichlorobis(?-cyclopentadienyl)titanium and iron

Doi:10.1016/S0022-1139(00)81260-9
(1991)
Palladium-catalysed asymmetric allylic alkylation using new chiral phosphinite-nitrogen ligands derived from D-glucosamine

Doi:10.1039/a810041a
(1999)
Determination of Absolute Stereochemistry of Acyclic 1,3-Polyols by a Difference CD Method

Doi:10.1021/ja00035a062
(1992)
A study on the relationship between the twisted π-conjugate system of 1,5-diaryl-1,5-diazapenta-1,3-dienes and their photophysical properties

Doi:10.1246/cl.2012.984
(2012)
Synthesis and properties of some novel pyrazolone-based heterocyclic azo disperse dyes containing a fluorosulfonyl group

Doi:10.1016/j.dyepig.2012.06.009
(2012)
Tert-butyldimethylsilyl-directed highly enantioselective approach to axially chiral α-allenols

Doi:10.1002/chem.201201948
(2013)

Article Doi