TANDEM ALKYNE INSERTION AND ALLYL SULFONIUM YLIDE REARRANGEMENT OF γ,δ-ALKYNYL-α'-DIAZOKETONES

DOI: 10.1016/0040-4039(92)88041-3

Source and publish data:

Tetrahedron Letters p. 169 - 172 (1992)

Update date:2022-09-26

Topics:

Authors:

Hoye, Thomas R.

Dinsmore, Christopher J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)88041-3

Acetylenic α-diazaketones 1, when treated with catalytic rhodium carboxylate dimer and diallylsulfide (1.1 equiv), undergo sequential alkyne insertion/ylide formation/sigmatropic rearrangements to give γ-allylthio cyclic enones.This transformation was use

Full text of DOI:10.1016/0040-4039(92)88041-3

Products guided by the article

Product name:1-Decen-8-yn-5-one, 10-(methoxymethoxy)-6,6-dimethyl-4-(2-propenylthio)-

Cas No:139884-98-3

R&D Labs maybe for 139884-98-3

Zhangjiagang Jianing Import & Export Co.,Ltd.

Contact:086-512-55379012 13913607595

Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.

Contact:15857995878 0579-82207761

Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
SJZ THLD IMP & EXP CO LTD

website:http://www.truewingroup.com

Contact:86-311-66699812

Address:NO.600 ZHONGSHAN EAST ROAD SHIJIAZHUANG
zhejiang huangyan wanfeng pharm chem co.ltd

Contact:+86-576- 84160728

Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
Beijing Stable Chemcial Co.ltd

Contact:86-10-63785052

Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China

Relevant to this article

Electronic Communication in Luminescent Dicyanorhenate-Bridged Homotrinuclear Rhenium(I) Complexes

Doi:10.1021/acs.inorgchem.9b00072
(2019)
Novel nucleophilic additions to [η⁴-2-(phenylsulfonyl)-1,3-butadiene] tricarbonyliron(O) complex

Doi:10.1016/S0040-4039(00)92332-3
(1992)
An efficient and modified biginelli-type synthesis of 3,4-dihydro-1H-indeno[1,2-d]pyrimidine-2,5-dione using phosphorous pentoxide

Doi:10.1080/00397911.2014.947652
(2014)
Novel codrugs with GABAergic activity for dopamine delivery in the brain

Doi:10.1016/j.ijpharm.2012.08.023
(2012)
Stereoselective Radical Cyclization Cascades Triggered by Addition of Diverse Radicals to Alkynes to Construct 6(5)-6-5 Fused Rings

Doi:10.1021/acs.orglett.6b02599
(2016)
Synthesis of the C1-C26 hexacyclic subunit of pectenotoxin 2

Doi:10.1021/ol302751b
(2012)

Article Doi