
Journal of Organic Chemistry p. 3214 - 3217 (1992)
Update date:2022-07-30
Topics:
Maynard, David F.
Norman, Anthony W.
Okamura, William H.
The bridged ether 6, produced via light-induced lead tetraacetate oxidation of Grundmann's alcohol 5, was transformed in three to four steps to the CD-ring ketones 9b and 10 which were then transformed via Horner-Wittig coupling to the 18-acetoxy analogue
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