Synthesis and palladium-catalyzed cycloaddition of the bifunctional conjunctive reagent methyl (Z)-1-methyl-2-trimethylsilylmethyl-2-butenyl carbonate

DOI: 10.1055/s-1992-34152

Source and publish data:

Synthesis p. 151 - 156 (1992)

Update date:2022-09-26

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Authors:

Trost Trost

Matelich

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Article abstract of DOI:10.1055/s-1992-34152

A simple synthesis of (Z)-2-trimethylsilylmethyl-2-buten-1-ol from 2-butyn-1-ol provides ready access to disubstituted bifunctional conjunctive reagents such as the title compounds. Palladium(0) catalysts initiate cycloaddition to electron-deficient olefi

Full text of DOI:10.1055/s-1992-34152

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