Electronic effects in the regioselectivity of nucleophilic attacks on cationic 1,3-diaryl-π-allylpalladium complexes

DOI: 10.1016/S0040-4020(01)88728-7

Source and publish data:

Tetrahedron p. 1695 - 1706 (1992)

Update date:2022-09-26

Topics:

Authors:

Prat Prat

Ribas Ribas

Moreno-Manas

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Article abstract of DOI:10.1016/S0040-4020(01)88728-7

Nucleophilic attacks on π-allylpalladium complexes derived from O₂N-Ph-(CH-CH-CH)-Ph-X systems (X = 4-OMe and 4-Cl) occur preferentially at the allylic terminus remote from the electron-withdrawing group (NO₂).

Full text of DOI:10.1016/S0040-4020(01)88728-7

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