Asymmetric Fuctionalisation of Prochiral 1,3-Diols Based on an Efficient 1,6-Chiral Induction: the Diastereoselective C-O Bond Fission in Chiral β-Arylsulfinyl Acetal via Two Types of Chelation Control

DOI: 10.1039/c39920000516

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 516 - 518 (1992)

Update date:2022-08-06

Topics:

Authors:

Iwata, Chuzo

Maezaki, Naoyoshi

Murakami, Manabu

Soejima, Motohiro

Tanaka, Tetsuaki

Imanishi, Takeshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000516

The novel asymmetric functionalisation of a prochiral 1,3-diol is accomplished by the diastereoselective C-O bond fission of the chiral β-arylsulfinyl acetal via two types of chelation controlled transition states (A and C in Scheme 4).

Full text of DOI:10.1039/c39920000516

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1,3-Dioxane-5-propanoic acid, 2,2-dimethyl-, ethyl ester

Cas No:141096-58-4

R&D Labs maybe for 141096-58-4

taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China
Shanghai Dianyang Industry Co.,ltd

Contact:+86 21 6492 4669

Address:Chejing RD, Songjiang District, Shanghai, China
Lyrin Industrial Corporation Limited

Contact:86-731-82571800

Address:Rm 2408,Asia Economy International Building,Shaoshan Road South,Yuhua District,Changsha,Hunan,China
Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Changzhou Anyi Biochem Co., Ltd.(expird)

Contact:+86-519-88836158

Address:no,51 caoda

Relevant to this article

Atypical carbon-carbon bond scission and deoxygenation in the protonation of tungsten-η¹-oxabicyclic compounds

Doi:10.1039/CC9960001041
(1996)
Synthesis and characterization of triosmium clusters containing a nitrite ligand; crystal and molecular structures of [N(PPh₃)₂][Os₃(CO)₁₀(μ-η ²-NO₂)] and [Os₃(μ-H)(CO)₁₀(μ-η²-NO₂)]

Doi:10.1039/DT9960002177
(1996)
Stereogenic propargylic centers via base-mediated terminal allne isomerization

Doi:10.1021/jo960276i
(1996)
Dendrophanes: Novel steroid-recognizing dendritic receptors. Preliminary communication

Doi:10.1002/hlca.19960790320
(1996)
Synthesis and assessment of two malonyl dihydrazide derivatives as corrosion inhibitors for carbon steel in acidic media: Experimental and theoretical studies

Doi:10.3390/molecules26113183
(2021)
Synthesis of azolylalkylquinolines with cytotoxic activity

Doi:10.1002/jhet.5570330233
(1996)

Article Doi