Journal of the Chemical Society. Chemical communications p. 516 - 518 (1992)
Update date:2022-08-06
Topics:
Iwata, Chuzo
Maezaki, Naoyoshi
Murakami, Manabu
Soejima, Motohiro
Tanaka, Tetsuaki
Imanishi, Takeshi
The novel asymmetric functionalisation of a prochiral 1,3-diol is accomplished by the diastereoselective C-O bond fission of the chiral β-arylsulfinyl acetal via two types of chelation controlled transition states (A and C in Scheme 4).
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