Asymmetric Fuctionalisation of Prochiral 1,3-Diols Based on an Efficient 1,6-Chiral Induction: the Diastereoselective C-O Bond Fission in Chiral β-Arylsulfinyl Acetal via Two Types of Chelation Control

DOI: 10.1039/c39920000516

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 516 - 518 (1992)

Update date:2022-08-06

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Authors:

Iwata, Chuzo

Maezaki, Naoyoshi

Murakami, Manabu

Soejima, Motohiro

Tanaka, Tetsuaki

Imanishi, Takeshi

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Article abstract of DOI:10.1039/c39920000516

The novel asymmetric functionalisation of a prochiral 1,3-diol is accomplished by the diastereoselective C-O bond fission of the chiral β-arylsulfinyl acetal via two types of chelation controlled transition states (A and C in Scheme 4).

Full text of DOI:10.1039/c39920000516

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