Radical cyclisation of hept-1-enitols

DOI: 10.1016/0008-6215(92)84055-W

Source and publish data:

Carbohydrate Research p. 57 - 78 (1992)

Update date:2022-07-30

Topics:

Authors:

Redlich, Hartmut

Sudau, Wolfgang

Szardenings, Anna Katrin

Vollerthun, Roland

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Article abstract of DOI:10.1016/0008-6215(92)84055-W

7-Deoxy-7-iodohept-1-enitols react intramolecularly to give 5-carba analogues of pyranoses (pseudo sugars) by the action of tributyltin hydride, which generates a radical at C-7.The configuration at the new chiral centre depends on the relative orientatio

Full text of DOI:10.1016/0008-6215(92)84055-W

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