Formal total synthesis of (-)-dendrobine using zirconium-promoted reductive cyclization

DOI: 10.1021/jo00098a022

Source and publish data:

Journal of Organic Chemistry p. 5633 - 5642 (1994)

Update date:2022-08-03

Topics:

Authors:

Uesaka Uesaka

Saitoh Saitoh

Mori Mori

Shibasaki

Okamura Okamura

Date Date

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Article abstract of DOI:10.1021/jo00098a022

The alkaloid (-)-dendrobine was synthesized from (+)-calvone by a short sequence using zirconium-promoted reductive cyclization. The absolute configuration of a synthetic intermediate was determined by an improved version of Mosher's method.

Full text of DOI:10.1021/jo00098a022

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