Formal total synthesis of (-)-dendrobine using zirconium-promoted reductive cyclization

DOI: 10.1021/jo00098a022

Source and publish data:

Journal of Organic Chemistry p. 5633 - 5642 (1994)

Update date:2022-08-03

Topics:

Authors:

Uesaka Uesaka

Saitoh Saitoh

Mori Mori

Shibasaki

Okamura Okamura

Date Date

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00098a022

The alkaloid (-)-dendrobine was synthesized from (+)-calvone by a short sequence using zirconium-promoted reductive cyclization. The absolute configuration of a synthetic intermediate was determined by an improved version of Mosher's method.

Full text of DOI:10.1021/jo00098a022

Products guided by the article

Product name:(3R,5S)-3-(N-Allyl-N-benzylamino)-5-isopropenyl-2-methylcyclohexene

Cas No:141508-37-4

R&D Labs maybe for 141508-37-4

Hangzhou Yanshan Chemical Co.,Ltd.

Contact:86-571- 87698076

Address:Room 1001, #1 Building, Zhongtian MCC, No.2 Youzhinong, Wenyi West Road, Xihu District, Hangzhou, China
Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
Tianjin Jiuri New Materials Co., Ltd.

Contact:+86-22-58889220

Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.
Nanjing Zelang Medical Technology Co. Ltd

Contact:86-25-83063290/13770714480

Address:Ganjiabian 108# 01 Unit,701-702 room,Yao Hua Street,Qixia District,Nanjing,Jiangsu,China
VanderArk International Limited

Contact:86-10-82437576

Address:Qing He

Relevant to this article

Development of Dipeptidic hGPR54 Agonists

Doi:10.1002/cmdc.201600331
(2016)
Synthesis of 2-deoxy-2-[(2S,3R)-(2-fluoro-3-hydroxytetradecanoyl)amino]-3-O-[(3R)-3- tetradecanoyloxytetradecanoyl]-D-glucopyranose-4-(dihydrogen phosphate) and 2-deoxy-2-[(2R,3S)-(2-fluoro-3-hydroxytetradecanoyl)amino]-3-O-[(3R)-3- tetradecanoyloxytetrad

Doi:10.1248/cpb.40.333
(1992)
Synthesis and structure-activity relationships of tri-substituted thiazoles as RAGE antagonists for the treatment of Alzheimer's disease

Doi:10.1016/j.bmcl.2012.10.022
(2012)
Supramolecular chirality in organo-, hydro-, and metallogels derived from bis-amides of L -(+)-tartaric acid: Formation of highly aligned 1D silica fibers and evidence of 5-c net SnS topology in a metallogel network

Doi:10.1002/chem.201200871
(2012)
Enol-Ugi Reaction of Hydroxycoumarins: Straightforward Synthesis of Amino Acid Derived Coumarin Enamines

Doi:10.1055/s-0034-1380436
(2015)
Synthesis of N-formylated β-lactams using nano-sulfated TiO ₂ as catalyst under solvent-free conditions

Doi:10.1016/j.crci.2012.09.014
(2012)

Article Doi