Atom Transfer Addition and Annulation Reactions of Propargyl Iodomalononitrile

DOI: 10.1016/S0040-4020(01)88881-5

Source and publish data:

Tetrahedron p. 2157 - 2174 (1992)

Update date:2022-08-05

Topics:

Authors:

Curran, Dennis P.

Seong, Churl Min

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Article abstract of DOI:10.1016/S0040-4020(01)88881-5

Heating of propargyl iodomalononitrile with mono-, di- or trisubstituted alkenes followed by reduction of the crude or isolated products with tributyltin hydride produces dicyano(methylene)cyclopentanes in good to excellent overall yield.This radical annu

Full text of DOI:10.1016/S0040-4020(01)88881-5

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Product name:(Z)-trans-1,1-Dicyano-5-methyl-4-phenyl-3-(iodomethylene)cyclopentane

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