An efficient and stereoselective synthesis of 2′,5′-oligo-(SP)-thioadenylates

DOI: 10.1016/S0040-4020(01)92259-8

Source and publish data:

Tetrahedron p. 3209 - 3226 (1992)

Update date:2022-08-03

Topics:

Authors:

Battistini, Carlo

Brasca, Maria Gabriella

Fustinoni, Silvia

Lazzari, Ettore

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Article abstract of DOI:10.1016/S0040-4020(01)92259-8

2′,5′-Phosphorothioato-oligoadenylates have been synthesized with S_P-stereoselectivity by using hydrogenphosphonate methodoloy followed by oxidative sulphurization.

Full text of DOI:10.1016/S0040-4020(01)92259-8

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Product name:N⁶-benzoyl-3',5'-O-(1,1,3,3-tetraisopropyl-1,3-disilanediyl)-(S_P)-P-thioadenylyl-(2'-5')-N⁶-benzoyl-2',3'-O-(1,1,3,3-tetraisopropyl-1,3-disiloxanediyl)adenosine, triethylammonium salt

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