'Ene-type' addition of alkenes to phenyl vinylsulfoxide

DOI: 10.1016/S0040-4039(00)92228-7

Source and publish data:

Tetrahedron Letters p. 2511 - 2514 (1992)

Update date:2022-09-26

Topics:

Authors:

Brichard

Janousek

Merenyi Merenyi

Viehe Viehe

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)92228-7

Phenyl vinylsulfoxide reacts under acylating conditions (TFA, TFAA) with isobutene to give double 'ene' α,β-adduct. Propene and other alkenes examined afford a β-'ene' alkylation accompanied by trifluoroacetoxylation at the same carbon atom.

Full text of DOI:10.1016/S0040-4039(00)92228-7

Products guided by the article

Product name:Acetic acid, trifluoro-, 1-[1-(phenylthio)ethyl]-3-hexenyl ester

Cas No:142077-90-5

R&D Labs maybe for 142077-90-5

Shandong Topscience Biotech Co., Ltd.

Contact:0633-2619278

Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
Anhui Dexinjia Biopharm Co., Ltd

Contact:+86-531-82375818

Address:9 Hexie Road, kaifaqu, Taihe
Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
Arshine Pharmaceutical Co., Limited

website:http://www.cnarshine.com

Contact:0731-88503671

Address:Room 1109.Block C3, Lugu Enterprise Plaza,No.27 Wenxuan Road,Changsha National Hi-Tech Industrial Development Zone,Hunan ,P.R.China

Relevant to this article

Synthesis of (6R,all-E)-Neoxanthin and Related Allenic Carotenoids

Doi:10.1002/hlca.19920750314
(1992)
Stereoselective cyclopropyl phosphonate formation using (S)-dimethylsulfonium-(p-tolylsulfinyl)methylide. Unusual phosphoryl group migration

Doi:10.1016/j.tetlet.2012.11.002
(2013)
Reactions of 3-nitro- and 3-bromo-3-nitroacrylates with 1,3-cyclohexadiene

Doi:10.1134/S1070363212120213
()
Catalyst-Free Synthesis of Benzofuran Derivatives from Cascade Reactions between Nitroepoxides and Salicylaldehydes

Doi:10.1021/acs.joc.1c00143
(2021)
Features of the behavior of 4-amino-5-carboxamido1,2,3-triazolein multicomponent heterocyclizations with carbonyl compounds

Doi:10.3762/bjoc.8.236
(2012)
Construction of monocyclic eight-membered rings: Intermolecular rhodium(I)-catalyzed [6+2] cycloaddition of 4-allenals with alkynes

Doi:10.1002/anie.201206508
(2012)

Article Doi