'Ene-type' addition of alkenes to phenyl vinylsulfoxide

DOI: 10.1016/S0040-4039(00)92228-7

Source and publish data:

Tetrahedron Letters p. 2511 - 2514 (1992)

Update date:2022-09-26

Topics:

Authors:

Brichard

Janousek

Merenyi Merenyi

Viehe Viehe

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Article abstract of DOI:10.1016/S0040-4039(00)92228-7

Phenyl vinylsulfoxide reacts under acylating conditions (TFA, TFAA) with isobutene to give double 'ene' α,β-adduct. Propene and other alkenes examined afford a β-'ene' alkylation accompanied by trifluoroacetoxylation at the same carbon atom.

Full text of DOI:10.1016/S0040-4039(00)92228-7

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