Lewis acid promoted asymmetric 1,4-addition of allyltrimethylsilanes to chiral α,β-unsaturated n-acylamides

DOI: 10.1016/S0040-4039(00)92238-X

Source and publish data:

Tetrahedron Letters p. 2547 - 2548 (1992)

Update date:2022-07-29

Topics:

Authors:

Wu, Ming-Jung

Wu, Chi-Cheng

Lee, Pei-Chen

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Article abstract of DOI:10.1016/S0040-4039(00)92238-X

The 1,4-addition reaction of allytrimethylsilane to α,unsaturated N-acyloxazolidinones or N-enoylsultams in the presence of Lewis acid proceeds in good chemical yield with high diastereomeric excess. The absolute configuration of the new asymmetric center

Full text of DOI:10.1016/S0040-4039(00)92238-X

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