Efficient Preparation of a Key Intermediate Suitable for the Asymmetric Synthesis of (+)-Vernolepin and (-)-Vernomenin

DOI: 10.1039/c39920000697

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Journal of the Chemical Society. Chemical communications p. 697 - 698 (1992)

Update date:2022-08-03

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Authors:

Kato, Michiharu

Kido, Fusao

Masuda, Yoshiaki

Watanabe, Masataka

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Article abstract of DOI:10.1039/c39920000697

Starting with (1R,5S)-4,6,6-trimethyl-3-(phenylthio)bicyclo<3.1.1>hept-3-en-2-one, readily obtainable in large quantities from (+)-nopinone, (4aR,6RS,8aR)-6-methoxy-5-methylene-8a-vinyl-7-oxaoctahydronaphthalen-2(1H)-one, a promising key intermediate for

Full text of DOI:10.1039/c39920000697

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Product name:Bicyclo[3.1.1]hept-3-en-2-one, 4,6,6-trimethyl-3-(phenylsulfinyl)-, (1R)-

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