Rhodium(I) complex-catalyzed hydrosilylation of dimethyl muconates

DOI: 10.1016/0022-328X(92)83240-I

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C4 (1992)

Update date:2022-08-03

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Authors:

Yamamoto, Keiji

Tabei, Tatsuya

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Article abstract of DOI:10.1016/0022-328X(92)83240-I

Complete regioselective 1,6-hydrosilylation of dimethyl cis,cis-muconate took place by using trialkylsilanes in the presence of RhCl(PPh3)3 as a catalyst.The novel, functionalized ketene silyl acetal thus obtained exhibited moderate electrophilic properti

Full text of DOI:10.1016/0022-328X(92)83240-I

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