[2,3]-Sigmatropic rearrangements of 2-phosphineborane 2-propen-1-ols: Rapid access to enantioenriched diphosphine monoxide derivatives

DOI: 10.1021/ol400310h

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Organic Letters p. 1136 - 1139 (2013)

Update date:2022-08-03

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Article abstract of DOI:10.1021/ol400310h

Hydrophosphination of secondary propargylic alcohols generates phosphine-containing allylic alcohols that undergo facile [2,3]-sigmatropic rearrangements with chlorophosphines, furnishing highly enantioenriched, crystalline diphosphine monoxides. The conf

Full text of DOI:10.1021/ol400310h

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[2,3]-Sigmatropic rearrangements of 2-phosphineborane 2-propen-1-ols: Rapid access to enantioenriched diphosphine monoxide derivatives

DOI: 10.1021/ol400310h

Source and publish data:

Authors:

Article abstract of DOI:10.1021/ol400310h

Full text of DOI:10.1021/ol400310h

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