Chiral Induction in Photochemical Reactions. 10. The Principle of Isoinversion: A Model of Stereoselection Developed from the Diastereoselectivity of the Paterno-Buechi Reaction

DOI: 10.1021/ja00196a048

Source and publish data:

Journal of the American Chemical Society p. 5367 - 5373 (1989)

Update date:2022-08-04

Topics:

Authors:

Buschmann, Helmut

Scharf, Hans-Dieter

Hoffmann, Norbert

Plath, Martin Wolfgang

Runsink, Jan

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Article abstract of DOI:10.1021/ja00196a048

In the Paterno-Buechi reaction of the chiral phenylglyoxalates a-c with cyclic olefins 3-6, the diastereomeric oxetanes 3-6a-c and 3-6a'-c' are formed endo-phenyl selectively in high yields.The temperature dependence of the diastereoselectivity yields two

Full text of DOI:10.1021/ja00196a048

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