Journal of the American Chemical Society p. 5367 - 5373 (1989)
Update date:2022-08-04
Topics:
Buschmann, Helmut
Scharf, Hans-Dieter
Hoffmann, Norbert
Plath, Martin Wolfgang
Runsink, Jan
In the Paterno-Buechi reaction of the chiral phenylglyoxalates a-c with cyclic olefins 3-6, the diastereomeric oxetanes 3-6a-c and 3-6a'-c' are formed endo-phenyl selectively in high yields.The temperature dependence of the diastereoselectivity yields two
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