Explosive reactions of platinum-hydroxylamine compounds

DOI: 10.1016/0022-5088(91)90330-7

Source and publish data:

Journal of the Less-Common Metals p. 287 - 292 (1991)

Update date:2022-09-26

Topics:: Authors:

Knothe

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-5088(91)90330-7

During handling of a reaction product of Pt(IV)-hydrochloric acid with hydroxylamine NH₂OH) a serious accident occurred in a precious metal plant. Investigations for the reason for this accident showed that, during reactions of Pt(II)/Pt(IV)-chlorocomplexes with hydroxylamine at pH-values greater than 7, precipitation products of various compositions can form. During small additions of hydroxylamine Pt-oxidehydrates, which built in NH₂OH form and with an excess of NH₂OH, well defined Pt(II)-hydroxylamine-complexes form. Above a critical concentration of NH₂OH all precipitation products were explosive. In addition to their tendency to explode, the composition of these products can vary strongly so extreme care during their handling has to be taken.

Full text of DOI:10.1016/0022-5088(91)90330-7

Products guided by the article

Product name:Pt(NH₂OH)4(OH)2

Cas No:14283-17-1

R&D Labs maybe for 14283-17-1

Shandong Shouguang Songchuan Industrial Additives Co.,Ltd

Contact:+86-536-8566856

Address:Shouguang,Shandong,China
Wuxi Forest Biological Co.,Ltd

Contact:+86-510-81602300

Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
HAORUI ENTERPRISES LLC

Contact:(1) 206-3550089

Address:5115 NE 8TH PL, Renton, WA 98059 USA
Anhui Gusheng Import&Export CO.,LTD

Contact:86-551-63662296

Address:Jinzhai Road NO.162 ,hefei, china
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County

Relevant to this article

Biotransformation of a novel positive allosteric modulator of metabotropic glutamate receptor subtype 5 contributes to seizure-like adverse events in rats involving a receptor agonism-dependent mechanism

Doi:10.1124/dmd.113.052084
(2013)
Preparation of sugar-derived 1,2-diamines via indium-catalyzed aza-Henry-type reaction: Application to the synthesis of 6-amino-1,6- dideoxynojirimycin

Doi:10.1016/j.tetlet.2013.02.041
(2013)
Synthesis and in silico studies of Novel Ru(II) complexes of Schiff base derivatives of 3-[(4-amino-5-thioxo-1,2,4-triazole-3-yl)methyl]-2(3H)-benzoxazolone compounds as potent Glutathione S-transferase and Cholinesterases Inhibitor

Doi:10.1016/j.molstruc.2021.129943
(2021)
Reaction progress kinetic analysis of a copper-catalyzed aerobic oxidative coupling reaction with N-phenyl tetrahydroisoquinoline

Doi:10.1021/jo5018876
(2014)
Synthesis and metal complexes of thiourea ligands containing carbohydrate-derived substituents

Doi:10.1002/hlca.201200386
(2013)
Novel phosphorescent tetradentate bis-cyclometalated ?C ^*N?N-coordinated platinum complexes: Structure, photophysics, and a synthetic adventure

Doi:10.1016/j.poly.2012.06.078
(2013)

Article Doi

Explosive reactions of platinum-hydroxylamine compounds

DOI: 10.1016/0022-5088(91)90330-7

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0022-5088(91)90330-7

Full text of DOI:10.1016/0022-5088(91)90330-7

Products guided by the article

R&D Labs maybe for 14283-17-1

Relevant to this article

Hot Product