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A NEW ROUTE TO 1,1-DIFLUORO OLEFINS: APPLICATION TO THE SYNTHESIS OF 2'-DEOXY-2'-DIFLUOROMETHYLENE NUCLEOSIDES

DOI: 10.1016/S0040-4039(00)79824-8

Source and publish data:

Tetrahedron Letters p. 3101 - 3104 (1992)

Update date:2022-09-26

Topics:

Authors:

Sabol, Jeffrey S.Sabol, Jeffrey S.

McCarthy, James R.McCarthy, James R.

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Article abstract of DOI:10.1016/S0040-4039(00)79824-8

Methodology has been developed for the difluoromethylenation of ketone 2, resulting in the synthesis of cytidine derivative 1c.

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Full text of DOI:10.1016/S0040-4039(00)79824-8

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Product name:1-[(2R,3aR,9aR)-3-(Benzenesulfonyl-difluoro-methyl)-3-hydroxy-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-2-yl]-4-ethoxy-1H-pyrimidin-2-one

Cas No:142887-91-0

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