CHEMOENZYMATIC SYNTHESIS OF (-)-CARBOCYCLIC 7-DEAZAOXETANOCIN G

DOI: 10.1016/S0040-4039(00)74181-5

Source and publish data:

Tetrahedron Letters p. 2249 - 2252 (1992)

Update date:2022-07-29

Topics: Asymmetric synthesis Catalyst Chemoenzymatic synthesis Chemical Synthesis Enzymatic Reaction Deazapurine Chiral compound

Authors:

Chen, Xing

Siddiqi, Suhaib M.

Schneller, Stewart W.

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Article abstract of DOI:10.1016/S0040-4039(00)74181-5

The enantioselective synthesis of (-)-(1R,2S,3S)-2-amino-7-<2,3-bis(hydroxymethyl)cyclobutyl>pyrrolo<2,3-d>pyrimidin-4(3H)-one (5) as the 7-deaza analogue of carbocyclic oxetanocin G is described in 13 steps from trans-3,3-diethoxy-1,2-bis(hydroxymethyl)c

Full text of DOI:10.1016/S0040-4039(00)74181-5

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Product name:(+/-)-(1α,2α,3β)-2,3-bis<(benzyloxy)methyl>cyclobutanol

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