Tetrahedron Letters p. 4843 - 4846 (1992)
Update date:2022-08-03
Topics:
Hitchcock, Stephen A.
Pattenden, Gerald
Treatment of the iodo-trienone (8 b) with tri-n-butyltin hydride in the presence of AIBN is shown to produce the taxane ring system (11) by way of a tandem radical macrocyclisation - radical transannulation sequence, i.e. (8 b) → (9) → (11) (cf. Scheme 1)
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Doi:10.1002/chem.201601759
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