Hydrophosphinylation of unactivated terminal alkenes catalyzed by nickel chloride

DOI: 10.1021/jo4008749

Source and publish data:

Journal of Organic Chemistry p. 6599 - 6608 (2013)

Update date:2022-07-30

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Authors:

Ortial, Stephanie

Fisher, Henry C.

Montchamp, Jean-Luc

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Article abstract of DOI:10.1021/jo4008749

The room-temperature hydrophosphinylation of unactivated monosubstituted alkenes using phosphinates (ROP(O)H₂) and catalytic NiCl₂ in the presence of dppe is described. The method is competitive with prior palladium-catalyzed reactio

Full text of DOI:10.1021/jo4008749

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