An Intramolecular Schmidt Reaction of an Alkyl Azide with a Carbocation. The Generation and Rearrangement of a Conformationally Restricted Secondary Aminodiazonium Ion

DOI: 10.1016/S0040-4039(00)79075-7

Source and publish data:

Tetrahedron Letters p. 5291 - 5294 (1992)

Update date:2022-07-30

Topics:

Authors:

Pearson, William H.

Schkeryantz, Jeffrey M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79075-7

Treatment of azidoalkene 2 with triflic acid produced the bridged bicyclic enamine 3 by an intramolecular Schmidt reaction.Rearrangement of the intermediate aminodiazonium ion 5 is completely regioselective.

Full text of DOI:10.1016/S0040-4039(00)79075-7

Products guided by the article

Product name:1-<3,4-(Methylenedioxy)phenyl>-3-(2-hydroxyethyl)cyclohex-1-ene

Cas No:144412-93-1

R&D Labs maybe for 144412-93-1

Shijiazhuang Sdyano Fine Chemical Co., Ltd

Contact:+86-311-89830448

Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
uni source industries limited

Contact:86 21 3772 9386

Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
Esuccess Material Limited

Contact:852-29282288

Address:HONGKONG
Jintan Jinnuo Chemical Co., Ltd.

Contact:+86-519-80199901

Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China

Relevant to this article

Synthesis, spectral and biological studies of novel schiff base metal complexes derived from cephalexin and sugars

Doi:10.14233/ajchem.2013.13005
(2013)
Synthesis and antioxidant and antimicrobial evaluation of novel 4-substituted-1H-1,2,4-triazole derivatives

Doi:10.3906/kim-1202-62
(2012)
A chiral organic base catalyst with halogen-bonding-donor functionality: Asymmetric Mannich reactions of malononitrile with: N -Boc aldimines and ketimines

Doi:10.1039/c8cc00865e
(2018)
Facile and convenient synthetic methods for bis(trifluoroacetyl)ketene N,O-, N,S- and S,S-acetals and 2,2-bis(trifluoroacetyl)vinylamines and sulfides

Doi:10.1055/s-1992-26134
(1992)
Doi:10.1002/ardp.19302680304
(1930)
Copper-catalyzed tandem synthesis of highly functionalized bisamidines

Doi:10.1055/s-0032-1317952
(2013)

Article Doi