Formation of zirconocene η2-imine complexes by rearrangement of cyclic iminoacyl complexes

DOI: 10.1016/S0040-4039(00)61172-3

Source and publish data:

Tetrahedron Letters p. 5655 - 5658 (1992)

Update date:2022-08-04

Topics:

Authors:

Davis Davis

Whitby Whitby

Jaxa-Chamiec

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Article abstract of DOI:10.1016/S0040-4039(00)61172-3

Insertion of phenylisocyanide into bicyclic zirconacyclopentanes, obtained from a 1,7-octa- or 1,6-hepta-diene by reaction with dibutylzirconocene, affords initially an iminoacyl complex that rearranges on warming to form a zirconocene η²-imine complex which inserts unactivated alkenes and alkynes.

Full text of DOI:10.1016/S0040-4039(00)61172-3

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