Electroreductive silylation of activated olefins using a reactive metal anode

DOI: 10.1016/S0040-4039(00)61132-2

Source and publish data:

Tetrahedron Letters p. 5515 - 5516 (1992)

Update date:2022-07-31

Topics:

Authors:

Ohno Ohno

Nakahiro

Sanemitsu

Hirashima

Nishiguchi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)61132-2

Electroreductive silylation of α, β-unsaturated esters, nitriles and ketones in the presence of Me₃SiCl using a reactive metal anode (Mg, Zn, Al) in an undivided cell afforded the corresponding β-silyl compounds offering a valuable method for introduction of a silyl group into activated olefins.

Full text of DOI:10.1016/S0040-4039(00)61132-2

Products guided by the article

Product name:Benzenepropanoic acid, 4-methyl-b-(trimethylsilyl)-, ethyl ester

Cas No:144707-84-6

R&D Labs maybe for 144707-84-6

Chen jie

Contact:027-87677569

Address:Room 2203, yujingmingmen Buidling One, xiongchu Road, wuhan city, hubei province, China
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
Shanghai PengMo Biotechnology Co.,Ltd

website:http://www.pengmobio.lookchem.com

Contact:86-13052359378

Address:No.218 Hai Qu Road.Shanghai.China
Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
Shijiazhuang Yunxuan Im&Export Co.,Ltd.

Contact:+86-311-83037514

Address:No.6 Hongbin Road

Relevant to this article

Design, synthesis, and cytotoxicity of pyridine, pyrazole, and thiazole derivatives derived from N-alkyl-4,5,6,7-tetrahydro-1-benzothiophene

Doi:10.1007/s10593-013-1259-4
(2013)
Structure and thermotropic phase behavior of a homologous series of bioactive N-acyldopamines

Doi:10.1021/jp402750m
(2013)
Chemoselective oxidative hydrolysis of EWG protected α-arylamino vinyl bromides to α-arylamino-α′-bromoacetones

Doi:10.1016/j.tetlet.2013.05.118
(2013)
A mild and efficient procedure for the N-functionalization of S-perfluoroalkylated aryl sulfoximines

Doi:10.1055/s-0033-1338440
(2013)
The synthesis of 3-trimethylsilyl-4-dimethyl(phenyl)silyl-but-3-en-2-one, a β-functionalised Michael acceptor

Doi:10.1016/S0040-4020(01)80457-9
(1992)
Microwave-assisted synthesis of (2-butyl-5-nitrobenzo[b]furan-3-yl)-[4-(substituted ethynyl)phenyl]methanones

Doi:10.24820/ark.5550190.p010.681
(2018)

Article Doi