
Tetrahedron Letters p. 5515 - 5516 (1992)
Update date:2022-07-31
Topics:
Ohno
Nakahiro
Sanemitsu
Hirashima
Nishiguchi
Electroreductive silylation of α, β-unsaturated esters, nitriles and ketones in the presence of Me3SiCl using a reactive metal anode (Mg, Zn, Al) in an undivided cell afforded the corresponding β-silyl compounds offering a valuable method for introduction of a silyl group into activated olefins.
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(2018)