The invention of radical reactions. Part XXIV. Relative rates of acylation and radical deoxygenation of secondary alcohols

DOI: 10.1016/S0040-4020(01)90359-X

Source and publish data:

Tetrahedron p. 7435 - 7446 (1992)

Update date:2022-08-03

Topics:

Authors:

Barton Barton

Dorchak Dorchak

Jaszberenyi

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Article abstract of DOI:10.1016/S0040-4020(01)90359-X

Secondary alcohols were transformed into various thiocarbonyl derivatives. Reduction of these compounds using tributyltin hydride and an initiator afforded the corresponding deoxy-compounds. Half-life and competitive measurements showed that all these reactions were fast and could be run to completion.

Full text of DOI:10.1016/S0040-4020(01)90359-X

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