
Carbohydrate Research p. 251 - 253 (1992)
Update date:2022-08-04
Topics:
Miljkovic
Djurendic
Vukojevic
Gasi
Csanadi
This paper reports a formal electrophilic addition of ″hypoiodous acid″ to 3,4,6-tri-O-acetyl-D-glucal and 3,4-di-O-acetyl-6-O-tosyl-D-glucal. Depending on the buffer system used and the pH, a mixture of the 2-deoxy-2-iodo esters together with the corresponding 2-deoxy-2-iodo sugars were obtained. The compounds obtained could be used for the preparation of 2-deoxy sugars or Brigl's anhydrides.
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