Asymmetric Synthesis of Syn 1,2-Diols via the Reaction of Aldehydes with Chiral γ-(Tetrahydropyranyloxy)allylstannanes

DOI: 10.1021/jo00052a002

Source and publish data:

Journal of Organic Chemistry p. 7003 - 7005 (1992)

Update date:2022-07-31

Topics:

Authors:

Yamamoto, Yoshinori

Kobayashi, Katsumi

Okano, Hiroshi

Kadota, Isao

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Article abstract of DOI:10.1021/jo00052a002

Asymmetric synthesis of syn 1,2-diols 3 has been accomplished via the reaction of the chiral γ-alkoxy-substituted allylstannane 1 with aldehydes in the presence of AlCl3 or AlCl3*OEt2, followed by a five-step operation to remove the chiral auxiliary.

Full text of DOI:10.1021/jo00052a002

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