Journal of Fluorine Chemistry p. 91 - 99 (1992)
Update date:2022-08-04
Topics:
Munavalli, Shekar
Rossman, David I.
Rohrbaugh, Dennis K.
Ferguson, C. Parker
Szafraniec, Leonard J.
Trifluoromethyl mono-, di- and tri-sulfides, and alkyl sulfides and disulfides, as well as dimerized products, are formed as a result of the simultaneous cleavage of the C-S and S-S bonds of bis(trifluoromethyl)trisulfide by Grignard reagents at -78 deg C.The formation of various products has been rationalized on the basis of the involvement of free radicals.
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