Triethylborane-induced radical cyclization of 1-allyloxy-2-halosilacyclopentane. Stereoselective synthesis of 1,3,6-triols starting from silacyclobutane

DOI: 10.1246/bcsj.68.625

Source and publish data:

Bulletin of the Chemical Society of Japan p. 625 - 634 (1995)

Update date:2022-08-02

Topics:

Authors:

Matsumoto

Miura Miura

Oshima Oshima

Utimoto Utimoto

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Article abstract of DOI:10.1246/bcsj.68.625

1-Allyloxy-2-bromo-1-phenylsilacyclopentane was synthesized by a ring-enlargement reaction of 1-allyloxy-1-phenylsilacyclobutane with LiCHBr₂. The treatment of 1-allyloxy-2-bromo-1-phenylsilacyclopentane with n-Bu₃SnH in the presence

Full text of DOI:10.1246/bcsj.68.625

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Product name:1-((Z)-2-hexenyloxy)-1-phenylsilacyclobutane

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