Anti-Cram Selective Reaction of α-Sulfenyl Acetals with Silylated Carbon Nucleophiles

DOI: 10.1246/cl.1990.941

Source and publish data:

Chemistry Letters p. 941 - 944 (1990)

Update date:2022-07-30

Topics:

Authors:

Saigo, Kazuhiko

Kudo, Kazuaki

Hashimoto, Yukihiko

Kimoto, Hiroki

Hasegawa, Masaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1990.941

α-Sulfenyl acetals reacted smoothly with silylated carbon nucleophiles such as silyl enol ether, ketene silyl acetal, and allylsilane in the presence of a catalytic amount of Lewis acid mainly to give anti-Cram adducts with high diastereoselectivity by th

Full text of DOI:10.1246/cl.1990.941

Products guided by the article

Product name:(5S,6S)-5-Methoxy-2,2-dimethyl-6-methylsulfanyl-6-phenyl-hexan-3-one

Cas No:145866-57-5

R&D Labs maybe for 145866-57-5

Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Beijing Top Science biological technology co., LTD

Contact:+86-13439059536

Address:15-1705 jre three mile, Beijing 100000,CHINA
Chengdu Cogon Bio-tech Co., Ltd.

Contact:86-28-85171192

Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.
Aminodiscovery Co.,Ltd.

Contact:+86-535-8888888

Address:No.161 Haishi Rd.
Chongqing KonAo Health Co.,Ltd

Contact:13687578375

Address:wuhan hubei china

Relevant to this article

The Arbuzov Reaction of Alkyl Diphenylphosphinites with 10-Methylacridinium Ion. Kinetic Study on the Formation and the Decomposition of Phosphonium Intermediates

Doi:10.1246/bcsj.66.2077
(1993)
Triazacyclane-based Trithiols and Their Use in the Preparation of Site-differentiated Iron-Sulfur Clusters

Doi:10.1039/DT9920003229
(1992)
Doi:10.1515/hc-2018-0099
(2018)
SYNTHESIS OF THE CHOLINE ESTER OF GLYCINE

Doi:10.1007/BF00777397
(1980)
Novel 2,6-bis(4-methoxyphenyl)-1-methylpiperidin-4-one oxime esters: Synthesis and a new insight into their antioxidant and antimicrobial potential

Doi:10.1007/s00044-013-0793-z
(2014)
Synthesis of new dithiolethione derivatives: 5-hydroxyiminoalkyl)-1,2-dithiole-3-thiones and 5-acyl-1,2-dithiole-3-thiones

Doi:10.1039/c39940000131
(1994)

Article Doi