Anti-Cram Selective Reaction of α-Sulfenyl Acetals with Silylated Carbon Nucleophiles

DOI: 10.1246/cl.1990.941

Source and publish data:

Chemistry Letters p. 941 - 944 (1990)

Update date:2022-07-30

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Authors:

Saigo, Kazuhiko

Kudo, Kazuaki

Hashimoto, Yukihiko

Kimoto, Hiroki

Hasegawa, Masaki

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Article abstract of DOI:10.1246/cl.1990.941

α-Sulfenyl acetals reacted smoothly with silylated carbon nucleophiles such as silyl enol ether, ketene silyl acetal, and allylsilane in the presence of a catalytic amount of Lewis acid mainly to give anti-Cram adducts with high diastereoselectivity by th

Full text of DOI:10.1246/cl.1990.941

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